Atomic Models Thomson’s Plum Pudding Model (1897) After discovering the electron, Thomson proposed that atoms consist of a uniform positive charge with electrons embedded within it, like plums in a pudding.
Rutherford Scattering (1911) Rutherford directed alpha particles at a thin gold foil. Most passed through, but some were Deflected at large angles, and a few bounced back.
Observations and conclusions :
Most alpha particles passed straight through: the atom is mostly empty space. Some were deflected: there is a small, dense, positively charged nucleus. Very few bounced back: the nucleus is very small compared to the atom. Nuclear atom model : A small, dense, positively charged nucleus surrounded by orbiting electrons.
The Bohr Model (1913) Bohr proposed a model for the hydrogen atom:
Electrons orbit the nucleus in certain allowed orbits (stationary states). Electrons do not radiate energy while in a stationary state. An electron can jump between orbits by absorbing or emitting a photon. The angular momentum is quantised: m v r = n h 2 π mvr = n\dfrac{h}{2\pi} m v r = n 2 π h Where n = 1 , 2 , 3 , … n = 1, 2, 3, \ldots n = 1 , 2 , 3 , … Energy Levels The energy of an electron in the n n n -th orbit of hydrogen:
E n = − { 1 3.6 { e V } } { n 2 } E_n = -\frac\{13.6\mathrm\{ eV\}\}\{n^2\} E n = − 1 { 3.6 { e V }} { n 2 } Level n n n Energy (eV) Ground state 1 − 13.6 -13.6 − 13.6 First excited 2 − 3.40 -3.40 − 3.40 Second excited 3 − 1.51 -1.51 − 1.51 Third excited 4 − 0.85 -0.85 − 0.85 Ionisation ∞ \infty ∞ 0 0 0
Photon Emission and Absorption When an electron transitions from level n i n_i n i to level n f n_f n f :
\Delta E = E_\{n_f\} - E_\{n_i\} = hf = \frac`\{hc}`\{\lambda\} Emission (n i > n f n_i \gt n_f n i > n f ): photon is released. Absorption (n i < n f n_i \lt n_f n i < n f ): photon is absorbed. Example
Find the wavelength of light emitted when an electron in hydrogen drops from n = 3 n = 3 n = 3 to n = 2 n = 2 n = 2 .
Δ E = E 2 − E 3 = − 3.40 − ( − 1.51 ) = − 1.89 { e V } \Delta E = E_2 - E_3 = -3.40 - (-1.51) = -1.89\mathrm\{ eV\} Δ E = E 2 − E 3 = − 3.40 − ( − 1.51 ) = − 1.89 { e V } (The energy of the photon is 1.89 e V 1.89\mathrm{ eV} 1.89 eV .)
\lambda = \frac`\{hc}`\{\Delta E\} = \frac\{1240\mathrm\{ eV\}\cdot\mathrm\{nm\}\}\{1.89\mathrm\{ eV\}\} = 656\mathrm\{ nm\} This is the red line in the Balmer series (visible spectrum of hydrogen).
Emission and Absorption Spectra Emission spectrum : bright lines on a dark background (photons emitted at specific wavelengths).Absorption spectrum : dark lines on a continuous spectrum (photons absorbed at specific wavelengths).Each element has a unique spectrum, like a fingerprint. Spectral Series of Hydrogen Series Transitions to Region Lyman n = 1 n = 1 n = 1 Ultraviolet Balmer n = 2 n = 2 n = 2 Visible Paschen n = 3 n = 3 n = 3 Infrared
Nuclear Structure Nucleons The nucleus contains:
Protons : positive charge + e +e + e Mass ≈ 1.673 × 10 − 27 k g \approx 1.673 \times 10^{-27}\mathrm{ kg} ≈ 1.673 × 1 0 − 27 kg Neutrons : no charge, mass ≈ 1.675 × 10 − 27 k g \approx 1.675 \times 10^{-27}\mathrm{ kg} ≈ 1.675 × 1 0 − 27 kg The atomic number Z Z Z = number of protons (determines the element).
The mass number A A A = number of protons + number of neutrons.
The neutron number N = A − Z N = A - Z N = A − Z .
Nuclear Notation Z A X ^A_Z X Z A X For example: 92 235 U ^{235}_{92}\mathrm U 92 235 U has 92 protons and 143 neutrons.
Isotopes Isotopes of an element have the same number of protons but different numbers of neutrons.
Isotope Protons Neutrons 1 1 H ^{1}_1\mathrm H 1 1 H (protium)1 0 1 2 H ^{2}_1\mathrm H 1 2 H (deuterium)1 1 1 3 H ^{3}_1\mathrm H 1 3 H (tritium)1 2
Nuclear Forces Strong nuclear force : short-range attractive force between nucleons. Overcomes electrostatic repulsion between protons. Range ≈ 1 \approx 1 ≈ 1 —3 f m 3\mathrm{ fm} 3 fm (1 f m = 10 − 15 m 1\mathrm{ fm} = 10^{-15}\mathrm{ m} 1 fm = 1 0 − 15 m ).Electrostatic (Coulomb) force : repulsive between protons, long range.Nuclear Radius The radius of a nucleus is approximately:
R = R 0 A { 1 / 3 } R = R_0 A^\{1/3\} R = R 0 A { 1/3 } Where R 0 ≈ 1.2 f m R_0 \approx 1.2\mathrm{ fm} R 0 ≈ 1.2 fm .
Nuclear Density Since R ∝ A 1 / 3 R \propto A^{1/3} R ∝ A 1/3 The volume V ∝ A V \propto A V ∝ A . All nuclei have approximately the same density:
ρ ≈ 2.3 × 10 { 17 } { k g / m } 3 \rho \approx 2.3 \times 10^\{17\}\mathrm\{ kg/m\}^3 ρ ≈ 2.3 × 1 0 { 17 } { k g / m } 3 Radioactivity Types of Radiation Property Alpha (α \alpha α ) Beta (β − \beta^- β − ) Gamma (γ \gamma γ ) Particle 2 4 H e ^4_2\mathrm{He} 2 4 He nucleusElectron (e − e^- e − ) Photon Charge + 2 e +2e + 2 e − e -e − e 0 0 0 Mass 4 u 4\mathrm{ u} 4 u ≈ 0 \approx 0 ≈ 0 0 0 0 Speed ≈ 0.05 c \approx 0.05c ≈ 0.05 c Up to ≈ 0.99 c \approx 0.99c ≈ 0.99 c c c c Penetration Paper Aluminium (few mm) Lead (few cm) Ionising power High Medium Low
Alpha Decay Z A X → { A − 4 } { Z − 2 } Y + 2 4 α ^A_Z X \to ^\{A-4\}_\{Z-2\} Y + ^4_2\alpha Z A X → { A − 4 } { Z − 2 } Y + 2 4 α The daughter nucleus has atomic number reduced by 2 and mass number reduced by 4.
Example
{ 14 } 6 C → { 14 } 7 N + { 0 − 1 } β + { ˉ ν } e ^\{14\}_6\mathrm C \to ^\{14\}_7\mathrm N + ^0_\{-1\}\beta + \bar\{\nu\}_e { 14 } 6 C → { 14 } 7 N + { 0 − 1 } β + { ˉ ν } e Beta-plus Decay (Positron Emission) Z A X → { A Z − 1 } Y + { 0 + 1 } β + + ν e ^A_Z X \to ^A_\{Z-1\} Y + ^0_\{+1\}\beta^+ + \nu_e Z A X → { A Z − 1 } Y + { 0 + 1 } β + + ν e A proton converts to a neutron, emitting a positron and a neutrino:
P → n + e + + ν e P \to n + e^+ + \nu_e P → n + e + + ν e Gamma Decay The nucleus transitions from a higher energy state to a lower energy state, emitting a gamma photon:
Z A X ∗ → Z A X + γ ^A_Z X^* \to ^A_Z X + \gamma Z A X ∗ → Z A X + γ No change in Z Z Z or A A A .
Half-Life The half-life t 1 / 2 t_{1/2} t 1/2 is the time for half of the radioactive nuclei in a sample to decay.
Exponential Decay Law N = N 0 e { − λ t } N = N_0 e^\{-\lambda t\} N = N 0 e { − λ t } Where:
N N N = number of undecayed nuclei at time t t t N 0 N_0 N 0 = initial number of nucleiλ \lambda λ = decay constantRelationship Between Half-Life and Decay Constant T { 1 / 2 } = { ln 2 } { λ } T_\{1/2\} = \frac\{\ln 2\}\{\lambda\} T { 1/2 } = ln { 2 } { λ } Activity The activity A A A is the number of decays per unit time:
A = \lambda N = \frac`\{dN}, \{dt}` SI unit: becquerel (B q \mathrm{Bq} Bq ), where 1 B q = 1 d e c a y / s 1\mathrm{ Bq} = 1\mathrm{ decay/s} 1 Bq = 1 decay/s .
Example
A sample has a half-life of 5 5 5 days and an initial activity of 800 B q 800\mathrm{ Bq} 800 Bq . Find the activity after 15 15 15 days.
A = A 0 e { − λ t } A = A_0 e^\{-\lambda t\} A = A 0 e { − λ t } λ = { ln 2 } { 5 } = 0.1386 { d a y } { − 1 } \lambda = \frac\{\ln 2\}\{5\} = 0.1386\mathrm\{ day\}^\{-1\} λ = ln { 2 } { 5 } = 0.1386 { d a y } { − 1 } A = 800 × e { − 0.1386 × 15 } = 800 × e { − 2.079 } = 800 × 0.125 = 100 { B q } A = 800 \times e^\{-0.1386 \times 15\} = 800 \times e^\{-2.079\} = 800 \times 0.125 = 100\mathrm\{ Bq\} A = 800 × e { − 0.1386 × 15 } = 800 × e { − 2.079 } = 800 × 0.125 = 100 { B q } Alternatively: 15 15 15 days = 3 = 3 = 3 half-lives, so A = 800 × ( 1 / 2 ) 3 = 100 B q A = 800 \times (1/2)^3 = 100\mathrm{ Bq} A = 800 × ( 1/2 ) 3 = 100 Bq .
Background Radiation Background radiation comes from natural and artificial sources:
Cosmic rays Radon gas (from rocks and soil) Medical procedures (X-rays) Nuclear waste and fallout Radioactive materials in the Earth Nuclear Reactions Fission A heavy nucleus splits into two (or more) lighter nuclei, releasing energy and neutrons.
Example :
{ 235 } { 92 } U + 0 1 n → { 141 } { 56 } { B a } + { 92 } { 36 } { K r } + 3 0 1 n + { e n e r g y } ^\{235\}_\{92\}\mathrm U + ^1_0 n \to ^\{141\}_\{56\}\mathrm\{Ba\} + ^\{92\}_\{36\}\mathrm\{Kr\} + 3^1_0 n + \mathrm\{energy\} { 235 } { 92 } U + 0 1 n → { 141 } { 56 } { B a } + { 92 } { 36 } { K r } + 3 0 1 n + { e n er g y } Chain Reaction The neutrons released in fission can cause further fission events, creating a chain reaction.
Critical mass : the minimum mass of fissile material needed to sustain a chain reaction.Controlled fission : used in nuclear power reactors (control rods absorb neutrons).Uncontrolled fission : nuclear weapons.Fusion Light nuclei combine to form a heavier nucleus, releasing energy.
Example (proton-proton chain in the Sun):
4 1 1 H → 2 4 { H e } + 2 { 0 + 1 } β + + 2 ν e + { e n e r g y } 4^1_1\mathrm H \to ^4_2\mathrm\{He\} + 2^0_\{+1\}\beta^+ + 2\nu_e + \mathrm\{energy\} 4 1 1 H → 2 4 { H e } + 2 { 0 + 1 } β + + 2 ν e + { e n er g y } Conditions for Fusion Extremely high temperatures (> 10 7 K \gt 10^7\mathrm{ K} > 1 0 7 K ) to overcome electrostatic repulsion. High density to increase collision rate. Sufficient confinement time. Binding Energy per Nucleon The binding energy per nucleon curve shows:
Light nuclei (up to Fe-56): fusion increases binding energy per nucleon (releases energy). Heavy nuclei (beyond Fe-56): fission increases binding energy per nucleon (releases energy). Iron-56 has the highest binding energy per nucleon (most stable nucleus). Nucleus Binding Energy per Nucleon (MeV) 1 2 H ^2_1\mathrm H 1 2 H 1.11 2 4 H e ^4_2\mathrm{He} 2 4 He 7.07 26 56 F e ^{56}_{26}\mathrm{Fe} 26 56 Fe 8.79 92 235 U ^{235}_{92}\mathrm U 92 235 U 7.59
Mass Defect and Binding Energy The mass defect Δ m \Delta m Δ m is the difference between the mass of a nucleus and the sum of the masses of its individual nucleons:
Δ m = Z m p + N m n − m { { n u c l e u s } } \Delta m = Zm_p + Nm_n - m_\{\mathrm\{nucleus\}\} Δ m = Z m p + N m n − m { { n u c l e u s }} The binding energy is:
E b = Δ m ⋅ c 2 E_b = \Delta m \cdot c^2 E b = Δ m ⋅ c 2 Example
Calculate the binding energy of the helium-4 nucleus. (m p = 1.00728 u m_p = 1.00728\mathrm{ u} m p = 1.00728 u m n = 1.00867 u m_n = 1.00867\mathrm{ u} m n = 1.00867 u , m α = 4.00151 u m_{\alpha} = 4.00151\mathrm{ u} m α = 4.00151 u 1 u = 931.5 M e V / c 2 1\mathrm{ u} = 931.5\mathrm{ MeV}/c^2 1 u = 931.5 MeV / c 2 )
Δ m = 2 ( 1.00728 ) + 2 ( 1.00867 ) − 4.00151 = 2.01456 + 2.01734 − 4.00151 = 0.03039 { u } \Delta m = 2(1.00728) + 2(1.00867) - 4.00151 = 2.01456 + 2.01734 - 4.00151 = 0.03039\mathrm\{ u\} Δ m = 2 ( 1.00728 ) + 2 ( 1.00867 ) − 4.00151 = 2.01456 + 2.01734 − 4.00151 = 0.03039 { u } E b = 0.03039 × 931.5 = 28.3 { M e V } E_b = 0.03039 \times 931.5 = 28.3\mathrm\{ MeV\} E b = 0.03039 × 931.5 = 28.3 { M e V } Binding energy per nucleon = 28.3 4 = 7.08 M e V = \dfrac{28.3}{4} = 7.08\mathrm{ MeV} = 4 28.3 = 7.08 MeV .
Mass-Energy Equivalence Einstein’s Equation E = m c 2 E = mc^2 E = m c 2 Where c = 3.0 × 10 8 m / s c = 3.0 \times 10^8\mathrm{ m/s} c = 3.0 × 1 0 8 m/s .
This shows that mass and energy are equivalent and can be converted into each other.
Energy-Mass Unit Conversion 1 { u } = 931.5 { M e V } / c 2 1\mathrm\{ u\} = 931.5\mathrm\{ MeV\}/c^2 1 { u } = 931.5 { M e V } / c 2 1 { e V } = 1.602 × 10 { − 19 } { J } 1\mathrm\{ eV\} = 1.602 \times 10^\{-19\}\mathrm\{ J\} 1 { e V } = 1.602 × 1 0 { − 19 } { J } The Photoelectric Effect Shine light of different wavelengths and intensities onto a metal surface and observe the emission of photoelectrons. Investigate how frequency, intensity, and the work function affect the maximum Kinetic energy.
Phenomenon When light above a certain frequency shines on a metal surface, electrons are emitted (photoelectrons).
Key Observations Electrons are emitted only if the frequency exceeds a threshold frequency f 0 f_0 f 0 . The maximum kinetic energy of photoelectrons depends on frequency, not intensity. Increasing intensity increases the number of photoelectrons (current), not their energy. Emission is instantaneous (no time delay). Einstein’s Explanation Light consists of photons, each with energy E = h f E = hf E = h f . A single photon can eject one electron if h f ≥ ϕ hf \ge \phi h f ≥ ϕ .
E { k , max } = h f − ϕ E_\{k,\max\} = hf - \phi E { k , max } = h f − ϕ Where ϕ = h f 0 \phi = hf_0 ϕ = h f 0 is the work function (minimum energy to free an electron from the metal).
Key Equations E { k , max } = { 1 } { 2 } m v { max } 2 = e V s E_\{k,\max\} = \frac\{1\}\{2\}mv_\{\max\}^2 = eV_s E { k , max } = 1 { } { 2 } m v { max } 2 = e V s Where V s V_s V s is the stopping potential.
H f = ϕ + E { k , max } Hf = \phi + E_\{k,\max\} H f = ϕ + E { k , max } Graph of E k , max E_{k,\max} E k , m a x vs f f f Gradient = h = h = h (Planck’s constant) x x x -intercept = f 0 = f_0 = f 0 (threshold frequency)y y y -intercept = − ϕ = -\phi = − ϕ Example
The work function of sodium is 2.28 e V 2.28\mathrm{ eV} 2.28 eV . Find the maximum kinetic energy of photoelectrons when light of wavelength 400 n m 400\mathrm{ nm} 400 nm is incident.
E { p h o t o n } } = { h c { λ } = { 1 240 e V ⋅ n m } { 400 { n m } } = 3.10 { e V } E_{\mathrm\{photon\}\} = \frac\{hc}\{\lambda\} = \frac\{1240\mathrm{ eV}\cdot\mathrm{nm}\}\{400\mathrm\{ nm\}\} = 3.10\mathrm\{ eV\} E { p h o t o n }} = h { c { λ } = 1 { 240 eV ⋅ nm } { 400 { nm }} = 3.10 { e V } E { k , max } = 3.10 − 2.28 = 0.82 { e V } E_\{k,\max\} = 3.10 - 2.28 = 0.82\mathrm\{ eV\} E { k , max } = 3.10 − 2.28 = 0.82 { e V } Wave-Particle Duality de Broglie Wavelength All matter has wave-like properties. The de Broglie wavelength of a particle:
\lambda = \frac\{h\}\{p\} = \frac\{h\}`\{mv}` Where h = 6.626 × 10 − 34 J ⋅ s h = 6.626 \times 10^{-34}\mathrm{ J}\cdot\mathrm s h = 6.626 × 1 0 − 34 J ⋅ s is Planck’s constant.
Example
Find the de Broglie wavelength of an electron moving at 2 × 10 6 m / s 2 \times 10^6\mathrm{ m/s} 2 × 1 0 6 m/s . (m e = 9.109 × 10 − 31 k g m_e = 9.109 \times 10^{-31}\mathrm{ kg} m e = 9.109 × 1 0 − 31 kg )
λ = { 6 .626 × 10 { − 34 } } { 9.109 × 10 { − 31 } × 2 × 10 6 } = { 6 .626 × 10 { − 34 } } { 1.822 × 10 { − 24 } } = 3.64 × 10 { − 10 } { m } = 0.364 { n m } \lambda = \frac\{6.626 \times 10^\{-34\}\}\{9.109 \times 10^\{-31\} \times 2 \times 10^6\} = \frac\{6.626 \times 10^\{-34\}\}\{1.822 \times 10^\{-24\}\} = 3.64 \times 10^\{-10\}\mathrm\{ m\} = 0.364\mathrm\{ nm\} λ = 6 { .626 × 1 0 { − 34 }} { 9.109 × 1 0 { − 31 } × 2 × 1 0 6 } = 6 { .626 × 1 0 { − 34 }} { 1.822 × 1 0 { − 24 }} = 3.64 × 1 0 { − 10 } { m } = 0.364 { nm } This is comparable to X-ray wavelengths, explaining electron diffraction.
Davisson-Germer Experiment Confirmed de Broglie’s hypothesis by observing the diffraction of electrons by a crystal lattice.
IB Exam-Style Questions Question 1 (Paper 1 style) Uranium-238 undergoes alpha decay. What is the daughter nucleus?
{ 238 } { 92 } U → { 234 } { 90 } { T h } + 2 4 α ^\{238\}_\{92\}\mathrm U \to ^\{234\}_\{90\}\mathrm\{Th\} + ^4_2\alpha { 238 } { 92 } U → { 234 } { 90 } { T h } + 2 4 α The daughter is thorium-234.
Question 2 (Paper 2 style) A radioactive isotope has a half-life of 8 hours. A sample initially has an activity of 1200 B q 1200\mathrm{ Bq} 1200 Bq .
(a) Find the activity after 24 hours.
N = { 2 4 } { 8 } = 3 { h a l f − l i v e s } N = \frac\{24\}\{8\} = 3 \mathrm\{ half-lives\} N = 2 { 4 } { 8 } = 3 { ha l f − l i v es } A = 1200 × ( { 1 } { 2 } ) 3 = 150 { B q } A = 1200 \times \left(\frac\{1\}\{2\}\right)^3 = 150\mathrm\{ Bq\} A = 1200 × ( 1 { } { 2 } ) 3 = 150 { B q } (b) Find the decay constant.
λ = { ln 2 } { t { 1 / 2 } } = { 0 .693 } { 8 × 3600 } = 2.41 × 10 { − 5 } { s } { − 1 } \lambda = \frac\{\ln 2\}\{t_\{1/2\}\} = \frac\{0.693\}\{8 \times 3600\} = 2.41 \times 10^\{-5\}\mathrm\{ s\}^\{-1\} λ = ln { 2 } { t { 1/2 }} = 0 { .693 } { 8 × 3600 } = 2.41 × 1 0 { − 5 } { s } { − 1 } (c) How many undecayed nuclei remain after 24 hours?
A = λ N ⟹ 150 = 2.41 × 10 { − 5 } × N A = \lambda N \implies 150 = 2.41 \times 10^\{-5\} \times N A = λ N ⟹ 150 = 2.41 × 1 0 { − 5 } × N N = { 1 50 } { 2.41 × 10 { − 5 } } = 6.22 × 10 6 N = \frac\{150\}\{2.41 \times 10^\{-5\}\} = 6.22 \times 10^6 N = 1 { 50 } { 2.41 × 1 0 { − 5 }} = 6.22 × 1 0 6 Question 3 (Paper 2 style) The work function of a metal surface is 4.5 e V 4.5\mathrm{ eV} 4.5 eV .
(a) Find the threshold frequency.
F 0 = { ϕ } { h } = { 4 .5 × 1.602 × 10 { − 19 } } { 6.626 × 10 { − 34 } } = { 7 .21 × 10 { − 19 } } { 6.626 × 10 { − 34 } } = 1.09 × 10 { 15 } { H z } F_0 = \frac\{\phi\}\{h\} = \frac\{4.5 \times 1.602 \times 10^\{-19\}\}\{6.626 \times 10^\{-34\}\} = \frac\{7.21 \times 10^\{-19\}\}\{6.626 \times 10^\{-34\}\} = 1.09 \times 10^\{15\}\mathrm\{ Hz\} F 0 = ϕ { } { h } = 4 { .5 × 1.602 × 1 0 { − 19 }} { 6.626 × 1 0 { − 34 }} = 7 { .21 × 1 0 { − 19 }} { 6.626 × 1 0 { − 34 }} = 1.09 × 1 0 { 15 } { H z } (b) Find the stopping potential when UV light of frequency 2.0 × 10 15 H z 2.0 \times 10^{15}\mathrm{ Hz} 2.0 × 1 0 15 Hz is Incident.
E { k , max } = h f − ϕ = ( 6.626 × 10 { − 34 } ) ( 2.0 × 10 { 15 } ) − 4.5 ( 1.602 × 10 { − 19 } ) E_\{k,\max\} = hf - \phi = (6.626 \times 10^\{-34\})(2.0 \times 10^\{15\}) - 4.5(1.602 \times 10^\{-19\}) E { k , max } = h f − ϕ = ( 6.626 × 1 0 { − 34 }) ( 2.0 × 1 0 { 15 }) − 4.5 ( 1.602 × 1 0 { − 19 }) = 1.325 × 10 { − 18 } − 7.21 × 10 { − 19 } = 6.04 × 10 { − 20 } { J } = 1.325 \times 10^\{-18\} - 7.21 \times 10^\{-19\} = 6.04 \times 10^\{-20\}\mathrm\{ J\} = 1.325 × 1 0 { − 18 } − 7.21 × 1 0 { − 19 } = 6.04 × 1 0 { − 20 } { J } V s = { E { k , max } } { e } = { 6 .04 × 10 { − 20 } } { 1.602 × 10 { − 19 } } = 0.377 { V } V_s = \frac\{E_\{k,\max\}\}\{e\} = \frac\{6.04 \times 10^\{-20\}\}\{1.602 \times 10^\{-19\}\} = 0.377\mathrm\{ V\} V s = E { { k , max }} { e } = 6 { .04 × 1 0 { − 20 }} { 1.602 × 1 0 { − 19 }} = 0.377 { V } Question 4 (Paper 2 style) Calculate the energy released when 235 U ^{235}\mathrm U 235 U undergoes fission to produce 141 B a ^{141}\mathrm{Ba} 141 Ba , 92 K r ^{92}\mathrm{Kr} 92 Kr And 3 neutrons.
Masses: 235 U = 235.044 u ^{235}\mathrm U = 235.044\mathrm{ u} 235 U = 235.044 u , 141 B a = 140.914 u ^{141}\mathrm{Ba} = 140.914\mathrm{ u} 141 Ba = 140.914 u 92 K r = 91.926 u ^{92}\mathrm{Kr} = 91.926\mathrm{ u} 92 Kr = 91.926 u , n = 1.00867 u n = 1.00867\mathrm{ u} n = 1.00867 u .
Δ m = 235.044 − ( 140.914 + 91.926 + 3 × 1.00867 ) \Delta m = 235.044 - (140.914 + 91.926 + 3 \times 1.00867) Δ m = 235.044 − ( 140.914 + 91.926 + 3 × 1.00867 ) = 235.044 − ( 140.914 + 91.926 + 3.026 ) = 235.044 − 235.866 = − 0.822 { u } = 235.044 - (140.914 + 91.926 + 3.026) = 235.044 - 235.866 = -0.822\mathrm\{ u\} = 235.044 − ( 140.914 + 91.926 + 3.026 ) = 235.044 − 235.866 = − 0.822 { u } Wait, that gives negative mass defect. Let me recalculate:
Δ m = 235.044 − 140.914 − 91.926 − 3 ( 1.00867 ) = 235.044 − 140.914 − 91.926 − 3.026 = − 0.822 { u } \Delta m = 235.044 - 140.914 - 91.926 - 3(1.00867) = 235.044 - 140.914 - 91.926 - 3.026 = -0.822\mathrm\{ u\} Δ m = 235.044 − 140.914 − 91.926 − 3 ( 1.00867 ) = 235.044 − 140.914 − 91.926 − 3.026 = − 0.822 { u } This indicates I should use the neutron as incoming:
Δ m = ( 235.044 + 1.00867 ) − ( 140.914 + 91.926 + 3 × 1.00867 ) \Delta m = (235.044 + 1.00867) - (140.914 + 91.926 + 3 \times 1.00867) Δ m = ( 235.044 + 1.00867 ) − ( 140.914 + 91.926 + 3 × 1.00867 ) = 236.053 − 235.866 = 0.187 { u } = 236.053 - 235.866 = 0.187\mathrm\{ u\} = 236.053 − 235.866 = 0.187 { u } E = 0.187 × 931.5 = 174 { M e V } E = 0.187 \times 931.5 = 174\mathrm\{ MeV\} E = 0.187 × 931.5 = 174 { M e V } Summary Concept Formula Bohr energy levels E n = − 13.6 e V n 2 E_n = \dfrac{-13.6\mathrm{ eV}}{n^2} E n = n 2 − 13.6 eV Photon energy E = h f = h c λ E = hf = \dfrac{hc}{\lambda} E = h f = λ h c Half-life t 1 / 2 = ln 2 λ t_{1/2} = \dfrac{\ln 2}{\lambda} t 1/2 = λ ln 2 Decay law N = N 0 e − λ t N = N_0 e^{-\lambda t} N = N 0 e − λ t Activity A = λ N A = \lambda N A = λ N Mass-energy E = m c 2 E = mc^2 E = m c 2 Binding energy E b = Δ m ⋅ c 2 E_b = \Delta m \cdot c^2 E b = Δ m ⋅ c 2 Photoelectric effect E k , max = h f − ϕ E_{k,\max} = hf - \phi E k , m a x = h f − ϕ de Broglie wavelength λ = h m v \lambda = \dfrac{h}{mv} λ = m v h Nuclear radius R = R 0 A 1 / 3 R = R_0 A^{1/3} R = R 0 A 1/3
Exam Strategy
For nuclear physics, always balance your nuclear equations (conservation of A A A and Z Z Z ). For Photoelectric effect problems, check units carefully (eV vs J). For decay calculations, Identify the half-life and number of half-lives elapsed.
Electron Energy Levels and Transitions (Extended) Energy Level Diagrams Energy level diagrams show the allowed energies of electrons in an atom:
The ground state is the lowest energy level (n = 1 n = 1 n = 1 ). Excited states are higher energy levels (n = 2 , 3 , … n = 2, 3, \ldots n = 2 , 3 , … ). The ionisation energy is the energy needed to remove an electron from the ground state to infinity. Transition lines represent photon absorption (upward) or emission (downward). Absorption Spectrum vs Emission Spectrum Feature Emission Absorption How produced Hot gas emits light Cool gas absorbs from continuous source Appearance Bright lines on dark background Dark lines on continuous spectrum Information Wavelengths emitted by the element Wavelengths absorbed by the element Use Identifying elements in stars/nebulae Identifying elements in atmospheres
Series Limits Each spectral series has a series limit (convergence limit) corresponding to transitions to/from the Continuum (ionised state).
For the Lyman series: λ l i m i t = h c 13.6 e V = 91.2 n m \lambda_{\mathrm{limit}} = \dfrac{hc}{13.6\mathrm{ eV}} = 91.2\mathrm{ nm} λ limit = 13.6 eV h c = 91.2 nm .
Nuclear Physics Extended Nuclear Binding Energy Curve The binding energy per nucleon curve reveals:
Light nuclei (A < 56 \lt 56 < 56 ): Can release energy through fusion (combining).Iron-56 : Peak of the curve, most stable nucleus.Heavy nuclei (A > 56 \gt 56 > 56 ): Can release energy through fission (splitting).Very light nuclei (A < 4 \lt 4 < 4 ): Have very low binding energy per nucleon, large energy release in fusion.Energy from Fission Example
Calculate the energy released when one nucleus of U-235 fissions into Ba-141 and Kr-92 with 3 Neutrons.
Masses: U-235 = 235.0439 u 235.0439\mathrm{ u} 235.0439 u Ba-141 = 140.9139 u 140.9139\mathrm{ u} 140.9139 u Kr-92 = 91.8970 u 91.8970\mathrm{ u} 91.8970 u N = 1.00867 u 1.00867\mathrm{ u} 1.00867 u .
Reactants: 235.0439 + 1.00867 = 236.0526 u 235.0439 + 1.00867 = 236.0526\mathrm{ u} 235.0439 + 1.00867 = 236.0526 u
Products: 140.9139 + 91.8970 + 3 ( 1.00867 ) = 140.9139 + 91.8970 + 3.0260 = 235.8369 u 140.9139 + 91.8970 + 3(1.00867) = 140.9139 + 91.8970 + 3.0260 = 235.8369\mathrm{ u} 140.9139 + 91.8970 + 3 ( 1.00867 ) = 140.9139 + 91.8970 + 3.0260 = 235.8369 u
Mass defect: 236.0526 − 235.8369 = 0.2157 u 236.0526 - 235.8369 = 0.2157\mathrm{ u} 236.0526 − 235.8369 = 0.2157 u
Energy released: 0.2157 × 931.5 = 200.9 M e V 0.2157 \times 931.5 = 200.9\mathrm{ MeV} 0.2157 × 931.5 = 200.9 MeV
Nuclear Reactors Key components:
Fuel rods : contain fissile material (U-235 or Pu-239).Moderator : slows down neutrons (water, heavy water, graphite).Control rods : absorb neutrons to control the rate of fission (boron, cadmium).Coolant : removes heat from the reactor (water, liquid sodium).Shielding : protects workers from radiation (concrete, lead).Nuclear Waste Type Half-life Handling High-level (fission products) Years to centuries Deep geological disposal Transuranic waste Thousands of years Deep geological disposal Low-level (contaminated materials) Days to years Compaction and shallow burial
Quantum Mechanics Concepts Wave-Particle Duality Both matter and electromagnetic radiation exhibit wave-like and particle-like properties depending on the experiment.
Phenomenon Wave Nature Particle Nature Light Diffraction, interference Photoelectric effect, Compton scattering Electrons Electron diffraction Quantised energy levels
Heisenberg Uncertainty Principle Δ x ⋅ Δ p ≥ { h } { 2 π } \Delta x \cdot \Delta p \ge \frac\{h\}\{2\pi\} Δ x ⋅ Δ p ≥ h { } { 2 π } It is fundamentally impossible to know both the exact position and exact momentum of a particle Simultaneously.
Compton Scattering When X-rays scatter off electrons, the scattered X-ray has a longer wavelength:
Δ λ = { h } { m e c } ( 1 − cos θ ) \Delta\lambda = \frac\{h\}\{m_e c\}(1 - \cos\theta) Δ λ = h { } { m e c } ( 1 − cos θ ) Additional IB Exam-Style Questions Question 5 (Paper 2 style) The isotope Po-210 undergoes alpha decay with a half-life of 138 days.
(a) Write the nuclear equation for the decay.
{ 210 } { 84 } { P o } → { 206 } { 82 } { P b } + 2 4 α ^\{210\}_\{84\}\mathrm\{Po\} \to ^\{206\}_\{82\}\mathrm\{Pb\} + ^4_2\alpha { 210 } { 84 } { P o } → { 206 } { 82 } { P b } + 2 4 α (b) A sample of Po-210 has an initial activity of 800 B q 800\mathrm{ Bq} 800 Bq . Find the activity after 1 Year (365 days).
Number of half-lives: n = 365 138 = 2.645 n = \dfrac{365}{138} = 2.645 n = 138 365 = 2.645 .
A = 800 × ( { 1 } { 2 } ) { 2.645 } = 800 × 0.162 = 129.6 { B q } A = 800 \times \left(\frac\{1\}\{2\}\right)^\{2.645\} = 800 \times 0.162 = 129.6\mathrm\{ Bq\} A = 800 × ( 1 { } { 2 } ) { 2.645 } = 800 × 0.162 = 129.6 { B q } (c) Find the number of Po-210 nuclei in the initial sample.
λ = { ln 2 } { 138 × 86400 } = 5.83 × 10 { − 8 } { s } { − 1 } \lambda = \frac\{\ln 2\}\{138 \times 86400\} = 5.83 \times 10^\{-8\}\mathrm\{ s\}^\{-1\} λ = ln { 2 } { 138 × 86400 } = 5.83 × 1 0 { − 8 } { s } { − 1 } N = { A } { λ } = { 8 00 } { 5.83 × 10 { − 8 } } = 1.37 × 10 { 10 } N = \frac\{A\}\{\lambda\} = \frac\{800\}\{5.83 \times 10^\{-8\}\} = 1.37 \times 10^\{10\} N = A { } { λ } = 8 { 00 } { 5.83 × 1 0 { − 8 }} = 1.37 × 1 0 { 10 } (d) Calculate the mass of the initial sample.
M = { N × 210 } { N A } = { 1 .37 × 10 { 10 } × 210 } { 6.022 × 10 { 23 } } = 4.78 × 10 { − 12 } { g } M = \frac\{N \times 210\}\{N_A\} = \frac\{1.37 \times 10^\{10\} \times 210\}\{6.022 \times 10^\{23\}\} = 4.78 \times 10^\{-12\}\mathrm\{ g\} M = N { × 210 } { N A } = 1 { .37 × 1 0 { 10 } × 210 } { 6.022 × 1 0 { 23 }} = 4.78 × 1 0 { − 12 } { g } Question 6 (Paper 1 style) Which of the following radiations has the highest ionising power and the lowest penetrating power?
A. Alpha particles B. Beta particles C. Gamma rays D. X-rays
Answer: A. Alpha particles are the most ionising and the least penetrating.
Question 7 (Paper 2 style) An electron is accelerated through a potential difference of 500 V 500\mathrm{ V} 500 V .
(a) Calculate the kinetic energy of the electron in eV and J.
E k = 500 { e V } = 500 × 1.602 × 10 { − 19 } = 8.01 × 10 { − 17 } { J } E_k = 500\mathrm\{ eV\} = 500 \times 1.602 \times 10^\{-19\} = 8.01 \times 10^\{-17\}\mathrm\{ J\} E k = 500 { e V } = 500 × 1.602 × 1 0 { − 19 } = 8.01 × 1 0 { − 17 } { J } (b) Calculate the de Broglie wavelength of the electron.
V = { { 2 E k } { m e } } = { { 2 × 8.01 × 10 { − 17 } } { 9.109 × 10 { − 31 } } } = { 1.759 × 10 { 14 } } = 1.326 × 10 7 { m / s } V = \sqrt\{\frac\{2E_k\}\{m_e\}\} = \sqrt\{\frac\{2 \times 8.01 \times 10^\{-17\}\}\{9.109 \times 10^\{-31\}\}\} = \sqrt\{1.759 \times 10^\{14\}\} = 1.326 \times 10^7\mathrm\{ m/s\} V = { 2 { E k } { m e }} = { 2 { × 8.01 × 1 0 { − 17 }} { 9.109 × 1 0 { − 31 }}} = { 1.759 × 1 0 { 14 }} = 1.326 × 1 0 7 { m / s } \lambda = \frac\{h\}`\{mv}` = \frac\{6.626 \times 10^\{-34\}\}\{9.109 \times 10^\{-31\} \times 1.326 \times 10^7\} = \frac\{6.626 \times 10^\{-34\}\}\{1.208 \times 10^\{-23\}\} = 5.49 \times 10^\{-11\}\mathrm\{ m\} This wavelength is comparable to atomic spacing, suitable for electron diffraction experiments.
Tip
Diagnostic Test Ready to test your understanding of Atomic and Nuclear Physics ? The contains the hardest questions
within the IB specification for this topic, each with a full worked solution.
Unit tests probe edge cases and common misconceptions. Integration tests combine Atomic and Nuclear Physics with other physics topics to test synthesis under exam conditions.
Intuition Atomic physics bridges the microscopic and macroscopic worlds. The Bohr model quantises electron orbits like seats on a staircase rather than a ramp, explaining why atoms emit only specific colours of light. Radioactivity is spontaneous nuclear decay, governed by probability rather than certainty, with half-life describing how quickly a sample decays. Nuclear fission splits heavy atoms and fusion joins light ones, both releasing energy because the binding energy per nucleon has a maximum near iron. The photoelectric effect proved light comes in packets, launching quantum mechanics.
Common Pitfalls Confusing atomic number (protons) with mass number (protons + neutrons).
Forgetting that radioactive decay is random and spontaneous. It cannot be predicted for individual nuclei.
Misunderstanding that half-life is constant regardless of the initial amount of substance.
Using the wrong equation from the data sheet. Take time to read the full equation, including conditions and variable definitions.
Misidentifying the system boundary when applying conservation laws. Define what is included before writing equations.
Neglecting air resistance or assuming ideal conditions when the question specifies a real-world scenario.
Worked Examples Worked examples demonstrating the application of key concepts are covered in the detailed sub-pages linked above.
Cross-References