Skip to content

Atomic and Nuclear Physics

Atomic Models

Thomson’s Plum Pudding Model (1897)

After discovering the electron, Thomson proposed that atoms consist of a uniform positive charge with electrons embedded within it, like plums in a pudding.

Rutherford Scattering (1911)

Rutherford directed alpha particles at a thin gold foil. Most passed through, but some were Deflected at large angles, and a few bounced back.

Observations and conclusions:

  1. Most alpha particles passed straight through: the atom is mostly empty space.
  2. Some were deflected: there is a small, dense, positively charged nucleus.
  3. Very few bounced back: the nucleus is very small compared to the atom.

Nuclear atom model: A small, dense, positively charged nucleus surrounded by orbiting electrons.

The Bohr Model (1913)

Bohr proposed a model for the hydrogen atom:

  1. Electrons orbit the nucleus in certain allowed orbits (stationary states).
  2. Electrons do not radiate energy while in a stationary state.
  3. An electron can jump between orbits by absorbing or emitting a photon.
  4. The angular momentum is quantised: mvr=nh2πmvr = n\dfrac{h}{2\pi} Where n=1,2,3,…n = 1, 2, 3, \ldots

Energy Levels

The energy of an electron in the nn-th orbit of hydrogen:

En=−{13.6{eV}}{n2}E_n = -\frac\{13.6\mathrm\{ eV\}\}\{n^2\}
LevelnnEnergy (eV)
Ground state1−13.6-13.6
First excited2−3.40-3.40
Second excited3−1.51-1.51
Third excited4−0.85-0.85
Ionisation∞\infty00

Photon Emission and Absorption

When an electron transitions from level nin_i to level nfn_f:

\Delta E = E_\{n_f\} - E_\{n_i\} = hf = \frac`\{hc}`\{\lambda\}
  • Emission (ni>nfn_i \gt n_f): photon is released.
  • Absorption (ni<nfn_i \lt n_f): photon is absorbed.

Nuclear Reactors

Key components:

  • Fuel rods: contain fissile material (U-235 or Pu-239).
  • Moderator: slows down neutrons (water, heavy water, graphite).
  • Control rods: absorb neutrons to control the rate of fission (boron, cadmium).
  • Coolant: removes heat from the reactor (water, liquid sodium).
  • Shielding: protects workers from radiation (concrete, lead).

Nuclear Waste

TypeHalf-lifeHandling
High-level (fission products)Years to centuriesDeep geological disposal
Transuranic wasteThousands of yearsDeep geological disposal
Low-level (contaminated materials)Days to yearsCompaction and shallow burial

Quantum Mechanics Concepts

Wave-Particle Duality

Both matter and electromagnetic radiation exhibit wave-like and particle-like properties depending on the experiment.

PhenomenonWave NatureParticle Nature
LightDiffraction, interferencePhotoelectric effect, Compton scattering
ElectronsElectron diffractionQuantised energy levels

Heisenberg Uncertainty Principle

Δx⋅Δp≥{h}{2π}\Delta x \cdot \Delta p \ge \frac\{h\}\{2\pi\}

It is fundamentally impossible to know both the exact position and exact momentum of a particle Simultaneously.

Compton Scattering

When X-rays scatter off electrons, the scattered X-ray has a longer wavelength:

Δλ={h}{mec}(1−cos⁡θ)\Delta\lambda = \frac\{h\}\{m_e c\}(1 - \cos\theta)

Additional IB Exam-Style Questions

Question 5 (Paper 2 style)

The isotope Po-210 undergoes alpha decay with a half-life of 138 days.

(a) Write the nuclear equation for the decay.

{210}{84}{Po}→{206}{82}{Pb}+24α^\{210\}_\{84\}\mathrm\{Po\} \to ^\{206\}_\{82\}\mathrm\{Pb\} + ^4_2\alpha

(b) A sample of Po-210 has an initial activity of 800Bq800\mathrm{ Bq}. Find the activity after 1 Year (365 days).

Number of half-lives: n=365138=2.645n = \dfrac{365}{138} = 2.645.

A=800×({1}{2}){2.645}=800×0.162=129.6{Bq}A = 800 \times \left(\frac\{1\}\{2\}\right)^\{2.645\} = 800 \times 0.162 = 129.6\mathrm\{ Bq\}

(c) Find the number of Po-210 nuclei in the initial sample.

λ={ln⁡2}{138×86400}=5.83×10{−8}{s}{−1}\lambda = \frac\{\ln 2\}\{138 \times 86400\} = 5.83 \times 10^\{-8\}\mathrm\{ s\}^\{-1\} N={A}{λ}={800}{5.83×10{−8}}=1.37×10{10}N = \frac\{A\}\{\lambda\} = \frac\{800\}\{5.83 \times 10^\{-8\}\} = 1.37 \times 10^\{10\}

(d) Calculate the mass of the initial sample.

M={N×210}{NA}={1.37×10{10}×210}{6.022×10{23}}=4.78×10{−12}{g}M = \frac\{N \times 210\}\{N_A\} = \frac\{1.37 \times 10^\{10\} \times 210\}\{6.022 \times 10^\{23\}\} = 4.78 \times 10^\{-12\}\mathrm\{ g\}

Question 6 (Paper 1 style)

Which of the following radiations has the highest ionising power and the lowest penetrating power?

A. Alpha particles B. Beta particles C. Gamma rays D. X-rays

Answer: A. Alpha particles are the most ionising and the least penetrating.

Question 7 (Paper 2 style)

An electron is accelerated through a potential difference of 500V500\mathrm{ V}.

(a) Calculate the kinetic energy of the electron in eV and J.

Ek=500{eV}=500×1.602×10{−19}=8.01×10{−17}{J}E_k = 500\mathrm\{ eV\} = 500 \times 1.602 \times 10^\{-19\} = 8.01 \times 10^\{-17\}\mathrm\{ J\}

(b) Calculate the de Broglie wavelength of the electron.

V={{2Ek}{me}}={{2×8.01×10{−17}}{9.109×10{−31}}}={1.759×10{14}}=1.326×107{m/s}V = \sqrt\{\frac\{2E_k\}\{m_e\}\} = \sqrt\{\frac\{2 \times 8.01 \times 10^\{-17\}\}\{9.109 \times 10^\{-31\}\}\} = \sqrt\{1.759 \times 10^\{14\}\} = 1.326 \times 10^7\mathrm\{ m/s\} \lambda = \frac\{h\}`\{mv}` = \frac\{6.626 \times 10^\{-34\}\}\{9.109 \times 10^\{-31\} \times 1.326 \times 10^7\} = \frac\{6.626 \times 10^\{-34\}\}\{1.208 \times 10^\{-23\}\} = 5.49 \times 10^\{-11\}\mathrm\{ m\}

This wavelength is comparable to atomic spacing, suitable for electron diffraction experiments.



Cross-References